In this process, molten metal is separated into small droplets and frozen rapidly before the drops come into contact with each other or with a solid surface. Typically, a thin stream of molten metal is disintegrated by subjecting it to the impact of high-energy jets of gas or liquid. In principle, the technique is applicable to all metals that can be melted and is used commercially for the production of iron; copper; alloy steels; brass; bronze; low-melting-point metals such as aluminum, tin, lead, zinc, and cadmium; and, in selected instances, tungsten, titanium, rhenium, and other high-melting-point materials.
By choosing suitable conditions, such as electrolyte composition and concentration, temperature, and current density, many metals can be deposited in a spongy or powdery state. Further processing—washing, drying, reducing, annealing, and crushing—is often required, ultimately yielding high-purity and high-density powders. Copper is the primary metal produced by electrolysis but iron, chromium, and magnesium powders are also produced this way. Due to its associated high energy costs, electrolysis is generally limited to high-value powders such as high-conductivity copper powders.
The most common chemical powder treatments involve oxide reduction, precipitation from solutions, and thermal decomposition. The powders produced can have a great variation in properties and yet have closely controlled particle size and shape. Oxide-reduced powders are often characterized as "spongy," due to pores present within individual particles. Solution-precipitated powders can provide narrow particle size distributions and high purity. Thermal decomposition is most often used to process carbonyls. These powders, once milled and annealed, exceed 99.5% purity.